Electrolysis - EdexcelPurifying copper by electrolysis
Electrolysis involves using electricity to break down electrolytes to form elements. The products of electrolysis can be predicted for a given electrolyte. Copper can be purified using electrolysis.
Copper is purified by electrolysisThe decomposition (breakdown) of a compound using an electric current.. Electricity is passed through solutions containing copper compounds, such as copper sulfate. The anodeThe positive electrode during electrolysis. (positive electrodeA conductor used to establish electrical contact with a circuit. The electrode attached to the negative terminal of a battery is called a negative electrode, or cathode. The electrode attached to the positive terminal of a battery is the positive electrode, or anode.) is made from impure copper and the cathodeThe negative electrode during electrolysis. (negative electrode) is made from pure copper.
Pure copper forms on the cathode. The slideshow shows how this works:
1. A beaker with pure and impure copper rods dipped into copper sulfate solution
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2. The pure copper rod is connected to the negative terminal of a battery and the impure rod is connected to the positive terminal
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3. The pure copper rod has increased in size while the impure rod has deteriorated, leaving a pool of anode sludge at the bottom of the beaker
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Slide1 of 3, Beaker with pure and impure copper rods dipping into copper(II) sulfate solution., Purifying copper by electrolysis 1. A beaker with pure and impure copper rods dipped into copper sulfate solution
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During electrolysis, the anode loses mass as copper dissolves, and the cathode gains mass as copper is deposited.
The slideshow shows what happens during the purification of copper by electrolysis:
1. Four Cu ions are attached to the rod on the right, and four Cu²+ ions are floating in the space between the rods
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2. A battery is connected between the rods and the Cu ions are pulled towards the left rod
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3. There are now four Cu ions attached to the left rod, with four Cu²+ ions floating in the middle
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Slide1 of 3, Two vertical copper rods. Four Cu ions are attached to the rod on the right, and four Cu2+ ions are floating in the space between the rods., The purification of copper by electrolysis 1. Four Cu ions are attached to the rod on the right, and four Cu²+ ions are floating in the space between the rods